Main Article Content

Abstract

Rhodamine B is a synthetic dye in the form of a powder, generally used for the purpose of changing colors in textile and paper factories. Rhodamine B is a chemical that is dangerous, absolutely should not be mixed in food, beverages and cosmetics, besides that rhodamine also has toxic properties so it must be degraded to reduce its toxicity. This research uses ZnO/Mn material which is synthesized using laser ablation in liquid (PLAL) technique as the degradation of rhodamine B waste. ZnO/Mn photocatalyst against rhodamine B dye. The results of the FE-SEM show that with the addition of Mn doping, the bond between the particles is getting better. ZnO/Mn with a variation of 0.1 mM obtained the best results for degradation, namely 89.474%, and the energy gap was 3.3196 eV.

Article Details

How to Cite
Nurafiah, N., Yudasari , N., Mutmainna, I., & Tahir, D. (2022). ZnO-Mn nanoparticles synthesized by pulsed laser ablation in liquid for photocatalytic degradation of Rhodamine B. Gravitasi, 21(1), 23-29. https://doi.org/10.22487/gravitasi.v21i1.15911

References

  1. H. Park, W. Choi, “Photocatalytic Reactivities of Nafion-Coated TiO2 for the Degradation Charged Organic Compounds Under UV or Visible Light”, J. Phys, Chem. B, 109 : 11667- 11674 (2005), DOI : https://doi.org/10.1021/jp051222s
  2. A. Rafiq, M. Ikram, S.Ali, F. Niaz, M.Khan, Q.Khan., “Photocatalytic Degradation Of Dyes Using Semiconductor Photocatalysts to Clean Industrial Water Pollution”., Journal of Industrial and Engineering Chemistry., Vol. 97, No.-, Hal. 111-128., (2021)., DOI : https://doi.org/10.1016/j.jiec.2021.02.017
  3. K. Qi , B. Cheng ,J. Yu , W. Ho. “Review on the improvement of the photocatalytic and antibacterial activities of ZnO”. Journal of Alloys and Compounds 727 (2017) 792-820., DOI : https://doi.org/10.1016/j.jallcom.2017.08.142
  4. N. Guo, H. Liu, Y. Fu, J. Hu . “Preparation of Fe2O3 nanoparticles doped with In2O3 and photocatalytic degradation property for rhodamine B”. International Journal for Light and Electron Optics 201 (2020) 163537., DOI: 10.1016/j.ijleo.2019.163537
  5. P.VE, T. Buruiana, E.C. Buruiana, “Photocatalytic degradation of Rhodamine B dye by polymeric films containing ZnO, Ag nanoparticles and polypyrrole, Journal of Photochemistry and amp”., Photobiology, A: Chemistry (2018) S1010-6030(17)31702-1., DOI : 10.1016/J.JPHOTOCHEM.2018.11.016
  6. E. Asikuzun, O. Ozturk, L. Arda, A. T. Tasci, F. Kartal and C. Terzioglu, “High-Quality cAxis Oriented Non-Vacuum Er Doped ZnO Thin Films”, Ceram. Inter. 2 (2016) 8085–8091.,DOI : https://doi.org/10.1016/j.ceramint.2016.02.008
  7. D. Akcan, A. Gungor, L. Arda, “Structural and optical properties of Na-doped ZnO films”, Journal of Molecular Structure 1161 (2018) 299-305., DOI: https://doi.org/10.1016/j.molstruc.2018.02.058
  8. M. Tosun, S.D. Senol, L. Arda, “Effect of Mn/Cu co-doping on the structural, optical and photocatalytic properties of ZnO nanorods”, Journal of Molecular Structure S0022-2860(2020)30396-3., DOI :
  9. 10.1016/j.molstruc.2020.128071
  10. H. Lahmar, M. Benamira, S. Douafer, L. Messaadia, A. Boudjerda, M. Trari, “Photocatalytic degradation of Methyl orange on the novel hetero-system La2NiO4 /ZnO under solar light”, Chemical Physics Letters S0009-2614(2020)30047-6., DOI : 10.1016/j.cplett.2020.137132
  11. M. Tariq, M. Muhammad, J. Khan, A.Raziq, M.K. Uddin, A. Niaz, S. S. Ahmed, A. Rahim., “Removal of Rhodamine B dye from Aqueous Solution Using Photo-Fenton Processes and Novel Ni-Cu@MWCNTs Photocatalyst”., Journal of Molecular Liquids., S0167-7322(20)31970-X, May 2020., doi: https://doi.org/10.1016/j.molliq.2020.113399.
  12. M. Shatnawi, A.M. Alsmadi, I. Bsoul, B. Salameh, M. Mathai, G. Alnawashi, Gassem M. Alzoubi, F. Al-Dweri, M.S. Bawa’aneh. “Influence of Mn doping on the magnetic and optical properties of ZnO 4 nanocrystalline particles”. Results in Physics (2016) No. 8., DOI : https://doi.org/10.1016/j.rinp.2016.11.041
  13. M. Kalita., P. C. Kalita, “Effects of size reduction on microstructural, optical, vibrational magnetic and photocatalytic properties of ZnO nanocrystals”, Mater. Charact. 137 (2018) 109 – 118., DOI: https://doi.org/10.1016/j.matchar.2018.01.013
  14. A. Kalita, P. Manos., C. Kalita, “Microstructural, optical, magnetic and photocatalytic properties of Mn doped ZnO nanocrystals of different sizes”, Mater. Charact S0921-4526(2018)30508-8., DOI: 10.1016/j.physb.2018.08.028
  15. L. Anju Chanua , W. Joychandra Singha , K. Jugeshwar Singhb , K. Nomita Devia,. “Effect of operational parameters on the photocatalytic degradation of Methylene blue dye solution using manganese doped ZnO nanoparticles”. Results in Physics 12 (2019) 1230–1237., DOI : https://doi.org/10.1016/j.rinp.2018.12.089
  16. R. Ulah, & J. Duta (2008). “Photocatalytic Degradation of Organic Dyes with Manganese Doped ZnO Nanoparticles”. Journal of Hazardous materials, 156(1-3), 194-200., DOI: https://doi.org/10.1016/j.rinp.2018.12.089
  17. [16] S. Senthikumaar, Rajendran., K. Banerjee, S., Chini, T. Kt., Sengodan, V., “Influence of Mn Doping on The Microstructure and Optical Property of ZnO”. Materials Science in Semiconductor Processing”, (2008)., Vol. 11, Hal.6-12., DOI : https://doi.org/10.48550/arXiv.0709.3901
  18. K. Rekha, M. Nirmala, M. G. Nair, A. Anukaliani, “Structural, optical, photocatalytic and antibacterial activity of zinc oxide and manganese doped zinc oxide nanoparticles”, Physica B 405(2010) 3180 – 3185., DOI : 10.1016/j.physb.2010.04.042
  19. N. A. Putri, V. Fauzia, S. Iwan, L. Roza, A. A. Umar, S. Budi, “Mn-doping-induced photocatalytic activity enhancement of ZnO nanorods prepared on glass substrates”, Appl. Surf. Sci. 439 (2018) 285 – 297., DOI : 10.1016/j.apsusc.2017.12.246
  20. X. Zhou, S. Ge, D. Yao, Y. Zuo, Y. Xiao, “Preparation, magnetic and optical properties of ZnO and ZnO:Co rods prepared by wet chemical method”, J. Alloys Compd. 463 (2008) L9 –L11., DOI : https://doi.org/10.1016/j.jallcom.2007.11.099
  21. R. Anugrahwidya , N. Yudasari , D. Tahir. “Optical and structural investigation of synthesis ZnO/Ag Nanoparticles prepared by laser ablation in liquid” Materials Science in Semiconductor Processing 105 (2020) 104712., DOI : 10.1016/j.mssp.2019.104712